15th September
Results
| Friendly | |||||
| 3 | 1883-1884 | Partick Thistle | 2-8 | detail | |
| Friendly | |||||
| 4 | 1888-1889 | CAMPSIE | 4-1 | detail | |
| Friendly | |||||
| 5 | 1894-1895 | LOCHWINNOCH | 7-1 | detail | |
| Central Combination League | |||||
| 2 | 1900-1901 | CAMELON | 4-4 | detail | |
| East of Scotland League | |||||
| 3 | 1906-1907 | Dundee | 0-2 | detail | |
| Scottish League Division One | |||||
| 5 | 1917-1918 | Airdrieonians | 1-3 | detail | |
| Scottish League Division One | |||||
| 6 | 1923-1924 | AYR UNITED | 2-0 | detail | |
| Friendly | |||||
| 1 | 1925-1926 | HEART OF MIDLOTHIAN | 1-2 | detail | |
| Stirlingshire Cup | |||||
| sf | 1926-1927 | ALLOA ATHLETIC | 3-0 | detail | |
| Scottish League Division One | |||||
| 6 | 1928-1929 | AYR UNITED | 5-2 | detail | |
| Scottish League Division One | |||||
| 8 | 1934-1935 | Kilmarnock | 1-4 | detail | |
| Scottish League Division One | |||||
| 7 | 1937-1938 | Aberdeen | 2-1 | detail | |
| Scottish League Southern Division A | |||||
| 6 | 1945-1946 | GREENOCK MORTON | 3-2 | detail | |
| Scottish League Cup | |||||
| qf | 1951-1952 | DUNDEE | 0-0 | detail | |
| Scottish League Division One | |||||
| 2 | 1956-1957 | AYR UNITED | 2-3 | detail | |
| Scottish League Division One | |||||
| 3 | 1962-1963 | QUEEN OF THE SOUTH | 2-2 | detail | |
| Scottish League Division One | |||||
| 3 | 1973-1974 | Clyde | 0-0 | detail | |
| Scottish League First Division | |||||
| 4 | 1976-1977 | GREENOCK MORTON | 3-5 | detail | |
| Scottish League Second Division | |||||
| 7 | 1979-1980 | Queen of the South | 0-2 | detail | |
| Scottish League First Division | |||||
| 3 | 1982-1983 | ALLOA ATHLETIC | 0-1 | detail | |
| Scottish League First Division | |||||
| 6 | 1984-1985 | MOTHERWELL | 0-3 | detail | |
| B&Q Scottish League First Division | |||||
| 4 | 1990-1991 | Kilmarnock | 1-1 | detail | |
| Scottish League Challenge Cup | |||||
| sf | 1997-1998 | Hamilton Academical | 2-1 | detail | |
| Bell's Scottish League First Division | |||||
| 6 | 2001-2002 | Airdrieonians | 1-2 | detail | |
| Clydesdale Bank Scottish Premier League | |||||
| 6 | 2007-2008 | HIBERNIAN | 1-1 | detail | |
| Irn-Bru Scottish League First Division | |||||
| 5 | 2012-2013 | Hamilton Academical | 1-1 | detail | |
| Ladbrokes Scottish Professional League Championship | |||||
| 5 | 2018-2019 | Ayr United | 2-3 | detail | |
| Friendly | |||||
| 1 | 2020-2021 | EAST STIRLINGSHIRE | 0-1 | detail | |